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dc.contributor.authorMartínez Laguna, Jonathan
dc.contributor.authorMollar Cuni, Andres
dc.contributor.authorVentura Espinosa, David
dc.contributor.authorMartín, Santiago
dc.contributor.authorCaballero Bevia, Ana 
dc.contributor.authorMata, Jose A.
dc.contributor.authorPérez Romero, Pedro José
dc.identifier.citationJ. Martínez-Laguna, A. Mollar-Cuni, D. Ventura-Espinosa, S. Martín, A. Caballero, J. A. Mata and P. J. Pérez, Dalton Trans., 2022, 51, 5250 DOI: 10.1039/D1DT04351Jes_ES
dc.identifier.issn1477-9234 (electrónico)
dc.description.abstractGold nanoparticles stabilized by NHC ligands and supported onto reduced graphene oxide (rGO) catalyse the functionalization of cyclohexane and benzene C-H bonds upon insertion of carbene CHCO2Et (from N2=CHCO2Et) groups. This is the first example in which such Csp3 or Csp2 bonds are functionalized with this strategy with nanoparticulated gold. This Au-NP@rGO material shows an exceptional activity, providing TON values 5-10 times higher than those already reported for molecular gold catalysts. Recyclability is also effective, reaching an accumulate TON value of 1400 after six consecutive useses_ES
dc.description.sponsorshipWe thank to Ministerio de Ciencia e Innovación for Grants PID2020-113797RB-C21, RTI2018-098237-B-C22 and PID2019-105881RB-I00 also financed by FEDER “Una manera de hacer Europa”. We also thank Junta de Andalucía (P18-RT-1536) and Universidad de Huelva (P.O.Feder UHU-1260216). JML thanks Ministerio de Ciencia e Innovación for FPI fellowship. A. M-C. thanks Generalitat Valenciana for grant (ACIF/2019/100). S. M. acknowledges DGA/fondos FEDER (Construyendo Europa desde Aragón) for funding the research group Platón (E31_20R).
dc.publisherRoyal Society of Chemistryes_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.titleGold nanoparticle-catalysed functionalization of carbon-hydrogen bonds by carbene transfer reactionses_ES
dc.subject.unesco23 Química

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