The TpxM Core in Csp3–H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tpx = Scorpionate Ligand; M = Cu, Ag)

Díaz Requejo, María Mar; Pérez Romero, Pedro José

doi:10.1002/ejic.201901168

Author

Díaz Requejo, María Mar ; Pérez Romero, Pedro José
Publication Date

2020-03
Publisher

Wiley
Citation

Díaz‐Requejo, M. M., & Pérez, P. J. (2020). The Tp x M Core in C sp 3 –H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tp x = Scorpionate Ligand; M = Cu, Ag). European Journal of Inorganic Chemistry, 2020(11–12), 879–885. https://doi.org/10.1002/ejic.201901168
Abstract

A comparison between three TpxM‐catalyzed (Tpx = scorpionate ligand; M = Cu, Ag) reactions leading to the functionalization of non‐activated, alkane Csp3–H bonds by carbene, nitrene or oxo insertion is presented. Analogies and differences in these transformations are discussed, including main reactive intermediates, selectivity trends and mechanistic interpretations.
URI

http://hdl.handle.net/10272/19643
Project

info:eu-repo/grantAgreement/MINECO [CTQ2017-82893-C2-1-R]

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The TpxM Core in Csp3–H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tpx = Scorpionate Ligand; M = Cu, Ag)

Author

Díaz Requejo, María Mar UHU Authority

; Pérez Romero, Pedro José UHU Authority

Publication Date

2020-03

Publisher

Wiley

Citation

Díaz‐Requejo, M. M., & Pérez, P. J. (2020). The Tp x M Core in C sp 3 –H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tp x = Scorpionate Ligand; M = Cu, Ag). European Journal of Inorganic Chemistry, 2020(11–12), 879–885. https://doi.org/10.1002/ejic.201901168

Abstract

A comparison between three TpxM‐catalyzed (Tpx = scorpionate ligand; M = Cu, Ag) reactions leading to the functionalization of non‐activated, alkane Csp3–H bonds by carbene, nitrene or oxo insertion is presented. Analogies and differences in these transformations are discussed, including main reactive intermediates, selectivity trends and mechanistic interpretations.

URI

http://hdl.handle.net/10272/19643

Project

info:eu-repo/grantAgreement/MINECO [CTQ2017-82893-C2-1-R]

Fichero	Tamaño	Formato	Ver	Description
143.pdf	794.1Kb	PDF	View/Open	versión postprint

Fichero	Tamaño	Formato	Ver	Description
143.pdf	794.1Kb	PDF	View/Open	versión postprint