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dc.contributor.authorLeón Gómez, Lara
dc.contributor.authorMozo Mulero, Cristina
dc.contributor.authorMartín Infante, F. J.
dc.contributor.authorMaraver Puig, Joaquín 
dc.contributor.authorCarbajo Timoteo, José Coronada 
dc.contributor.authorMozo Llamazares, Juan Daniel 
dc.date.accessioned2019-11-25T08:23:40Z
dc.date.available2019-11-25T08:23:40Z
dc.date.issued2019
dc.identifier.citationLeón, L., Mozo-Mulero, C., Martín-Infante, F. J., Maraver, J. J., Carbajo, J., & Mozo, J. D. (2019). Inexpensive FIA method to determine trace levels of imazapyr by UV-detection enhanced with electrochemical polarization. Arabian Journal of Chemistry, 12(7), 1042–1049. https://doi.org/10.1016/j.arabjc.2018.09.009es_ES
dc.identifier.issn1878-5352
dc.identifier.urihttp://hdl.handle.net/10272/17022
dc.description.abstractA new flow injection analysis method with spectro-electrochemical detection (FIA/SEC) to determine trace levels of imazapyr on water samples is presented. The non-chromatographic method involves the use of a bench photometer, a single-potential potentiostat, a low pressure pumping system and a home-made spectro-electrochemical flow detector (SEC-FD), specifically adapted for the described method and using a stainless steel/electrolytic lead/lead chloride (SS/e-Pb/PbCl2) working electrode. The limit of quantification (LOQ) reached for the optimized work parameters was 0.02 mg/mL, the relative standard deviation (RSD) in the whole range of linear response was less than 2% and a wide linear response range from 0.005 to 6.0 mg/mL was obtained. A standard addition method was used to determine the imazapyr amount in natural waters containing commercial formulation of such herbicide, the Recovery % has values close to 105%. The method performance makes it suitable to analyze the legal imazapyr tolerances established by the U.S. EPA avoiding the use of expensive chromatographic equipments and/or complicated sample preparations.es_ES
dc.description.sponsorshipThis work was supported by the Research Plan of the University of Huelva.
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.relation.isversionofPublisher’s versión
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherImazapyres_ES
dc.subject.otherFlow injection analysises_ES
dc.subject.otherHerbicide trace analysises_ES
dc.subject.otherUV detectiones_ES
dc.subject.otherLead electrodees_ES
dc.subject.otherWater micropollutants analysises_ES
dc.titleInexpensive FIA method to determine trace levels of imazapyr by UV-detection enhanced with electrochemical polarizationes_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherversionhttps://doi.org/10.1016/j.arabjc.2018.09.009es_ES
dc.identifier.doi10.1016/j.arabjc.2018.09.009
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES


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