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dc.contributor.authorFernández Sánchez, José María
dc.contributor.authorTejeda, Guzmán
dc.contributor.authorCarvajal Zaera, Miguel 
dc.contributor.authorSenent, María Luisa
dc.date.accessioned2019-05-23T07:02:23Z
dc.date.available2019-05-23T07:02:23Z
dc.date.issued2019
dc.identifier.citationFernández, J. M., Tejeda, G., Carvajal, M., & Senent, M. L. (2019). New Spectral Characterization of Dimethyl Ether Isotopologues CH3OCH3 and 13CH3OCH3 in the THz Region. The Astrophysical Journal Supplement Series, 241(1), 13. https://doi.org/10.3847/1538-4365/ab041ees_ES
dc.identifier.issn0067-0049
dc.identifier.issn1538-4365 (electrónico)
dc.identifier.urihttp://hdl.handle.net/10272/16294
dc.description.abstractThe torsional Raman spectra of two astrophysically detected isotopologues of dimethyl ether (DME, 12CH3O12CH3 and 13CH3O12CH3) have been recorded at room temperature and cooled in a supersonic jet and interpreted with the help of highly correlated ab initio calculations. DME displays excited torsional and vibrational levels at low energy that can be populated at the temperatures of the star-forming regions, obliging to extend the analysis of the rotational spectrum over the ground state. Its spectrum in the THz region is rather complex due to the coupling of the torsional overtones 2ν 11 and 2ν 15 with the COC-bending mode and the presence of many hot bands. The torsional overtones are set here at 2ν 11 = 385.2 cm−1 and 2ν 15 = 482.0 cm−1 for 12CH3O12CH3 and 2ν 11 = 385.0 cm−1 and 2ν 15 = 481.1 cm−1 for 13CH3O12CH3. The new assignment of 2ν 11 is downshifted around ~10 cm−1 with respect to the literature. All the other (hot) bands have been reassigned consistently. In addition, the infrared-forbidden torsional fundamental band ν 11 is observed here at 197.8 cm−1. The new spectral characterization in the THz region reported here provides improved values of the Hamiltonian parameters to be used in the analysis of the rotational spectra of DME isotopologues for further astrophysical detections.es_ES
dc.description.sponsorshipThis research is supported by the Spanish Ministerio de Economía y Competitividad (MINECO) under Grants FIS2014-53448-C2-2-P, FIS2016-76418-P and FIS2017- 84391-C2, and is partially financed by the Spanish Junta de Andalucía and the European Regional Development Fund (ERDF) under Grant SOMM17/6105/UGR. The authors also acknowledge the European COST Actions CM1401 “Our Astrochemical History” and CM1405 “MOLIM” and CTI (CSIC) and CESGA for computing facilities.
dc.language.isoenges_ES
dc.publisherIOP Publishinges_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherAstrochemistryes_ES
dc.subject.otherISM: lines and bandses_ES
dc.subject.otherISM: moleculeses_ES
dc.subject.otherMethods: laboratory: moleculares_ES
dc.subject.otherMolecular dataes_ES
dc.subject.otherTechniques: spectroscopices_ES
dc.titleNew Spectral Characterization of Dimethyl Ether Isotopologues CH3OCH3 and 13CH3OCH3 in the THz Regiones_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherversionhttps://doi.org/10.3847/1538-4365/ab041ees_ES
dc.identifier.doi10.3847/1538-4365/ab041e
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES


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