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dc.contributor.authorMaestre Cera, Lourdes 
dc.contributor.authorDorel, Ruth
dc.contributor.authorPablo, Óscar
dc.contributor.authorEscofet, Imma
dc.contributor.authorSameera, W. M. C.
dc.contributor.authorÁlvarez, Eleuterio
dc.contributor.authorMaseras, Feliu
dc.contributor.authorDíaz Requejo, María Mar 
dc.contributor.authorEchavarren, Antonio M.
dc.contributor.authorPérez Romero, Pedro José
dc.identifier.citationMaestre, L., Dorel, R., Pablo, Ó., Escofet, I., Sameera, W. M. C., Álvarez, E., … Pérez, P. J. (2017). Functional-Group-Tolerant, Silver-Catalyzed N–N Bond Formation by Nitrene Transfer to Amines. Journal of the American Chemical Society, 139(6), 2216-2223.
dc.description.abstractSilver(I) promotes the highly chemoselective N-amidation of tertiary amines under catalytic conditions to form aminimides by nitrene transfer from PhI=NTs. Remarkably, this transformation proceeds in a selective manner in the presence of olefins and other functional groups without formation of the commonly observed aziridines or C-H insertion products. The methodology can be applied not only to rather simple tertiary amines but also to complex natural molecules such as brucine or quinine, where the products derived from N-N formation were exclusively formed. Theoretical mechanistic studies have shown that this selective Namidation reaction proceeds through triplet silver-nitrenes.es_ES
dc.description.sponsorshipWe thank MINECO for Grants CTQ2014-52769-C3-1-R, CTQ2013-42106-P, CTQ2014-57761-R, Severo Ochoa Excellence Accreditation 2014-2018 (SEV-2013-0319), Red Intecat (CTQ2014-52974-REDC), FPI fellowship (L.M.), the European Research Council (Advanced Grant No. 321066), the AGAUR (2014 SGR 818), and CERCA Program/Generalitat de Catalunya. We also thank Dr. Tania Jimenez for additional experiments and the ICIQ X-ray diffraction unit for the crystal structures of compounds 5-7, 17b, 21, and 25.
dc.publisherAmerican Chemical Societyes_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.titleFunctional-Group-Tolerant, Silver-Catalyzed N–N Bond Formation by Nitrene Transfer to Amineses_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO [CTQ2014-52769-C3-1-R, CTQ2013-42106-P, CTQ2014-57761-R]

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