Direct, Copper-Catalyzed Oxidation of Aromatic C-H Bonds with Hydrogen Peroxide under Acid-Free Conditions

Conde Alcántara, Ana Isabel; Díaz Requejo, María Mar; Pérez Romero, Pedro José

doi:10.1039/c1cc12804c

Author

Conde Alcántara, Ana Isabel; Díaz Requejo, María Mar ; Pérez Romero, Pedro José
Publication Date

2011-06
Publisher

Royal Society of Chemistry
Citation

Conde Alcántara, A.I., Díaz Requejo, M.M., Pérez Romero, P.J.: "Direct, copper-catalyzed oxidation of aromatic C–H bonds with hydrogen peroxide under acid-free conditions". Chemical Communications. Vol. 47, págs. 8154-8156, (2011). DOI: 10.1039/C1CC12804C
Abstract

The direct oxidation of benzene into phenol using hydrogen peroxide has been achieved in the absence of any acid with TpxCu(NCMe) complexes as the catalysts. In the case of anthracenes as the substrates, valuable anthraquinones have been quantitatively obtained in the same manner
URI

http://hdl.handle.net/10272/11559

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Direct, Copper-Catalyzed Oxidation of Aromatic C-H Bonds with Hydrogen Peroxide under Acid-Free Conditions

Author

Conde Alcántara, Ana Isabel; Díaz Requejo, María Mar UHU Authority

; Pérez Romero, Pedro José UHU Authority

Publication Date

2011-06

Publisher

Royal Society of Chemistry

Citation

Conde Alcántara, A.I., Díaz Requejo, M.M., Pérez Romero, P.J.: "Direct, copper-catalyzed oxidation of aromatic C–H bonds with hydrogen peroxide under acid-free conditions". Chemical Communications. Vol. 47, págs. 8154-8156, (2011). DOI: 10.1039/C1CC12804C

Abstract

The direct oxidation of benzene into phenol using hydrogen peroxide has been achieved in the absence of any acid with TpxCu(NCMe) complexes as the catalysts. In the case of anthracenes as the substrates, valuable anthraquinones have been quantitatively obtained in the same manner

URI

http://hdl.handle.net/10272/11559

Fichero	Tamaño	Formato	Ver	Description
Direct_Copper-Catalyzed.pdf	235.7Kb	PDF	View/Open	versión post-print

Fichero	Tamaño	Formato	Ver	Description
Direct_Copper-Catalyzed.pdf	235.7Kb	PDF	View/Open	versión post-print