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dc.contributor.authorRivilla de la Cruz, Iván 
dc.contributor.authorGómez Emeterio, Bella Pilar
dc.contributor.authorRomero Fructos-Vázquez, Manuel 
dc.contributor.authorDíaz Requejo, María Mar 
dc.contributor.authorPérez Romero, Pedro José 
dc.date.accessioned2016-01-11T10:06:25Z
dc.date.available2016-01-11T10:06:25Z
dc.date.issued2011
dc.identifier.citationRivilla de la Cruz, I., Gómez Emeterio, B.P., Romero Fructos-Vazquez, M., Díaz Requejo, M.M., Pérez Romero, P.J.: "Exclusive Aromatic vs Aliphatic C–H Bond Functionalization by Carbene Insertion with Gold-Based Catalysts". Organometallics. Vol. 30 (10), págs. 2855–2860, (2011). DOI: 10.1021/om200206m
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041 (electrónico)
dc.identifier.urihttp://hdl.handle.net/10272/11556
dc.description.abstractThe direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, other Csp3-H bonds remaining unreacted. A study with a several NHC ligands in Au(I) and Au(III) complexes has been performed. A potential application in profen derivatives has also been developeden_US
dc.description.sponsorshipDGI (CTQ2008-00042BQU and Consolider Ingenio 2010, Grant CSD2006-0003) and Junta de Andalucía (P07-FQM-02870)
dc.language.isoengen_US
dc.publisherAmerican Chemical Society
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherGold catalysis
dc.subject.otherCarbene transfer
dc.subject.otherC-H functionalization
dc.subject.otherNHC ligands
dc.subject.otherDiazo compounds
dc.titleExclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalystsen_US
dc.typeinfo:eu-repo/semantics/articleen_US
dc.relation.publisherversionhttp://dx.doi.org/10.1021/om200206m
dc.identifier.doi10.1021/om200206m
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen_US


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