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dc.contributor.authorRivilla de la Cruz, Iván 
dc.contributor.authorGómez Emeterio, Bella Pilar
dc.contributor.authorRomero Fructos-Vázquez, Manuel 
dc.contributor.authorDíaz Requejo, María Mar 
dc.contributor.authorPérez Romero, Pedro José
dc.identifier.citationRivilla de la Cruz, I., Gómez Emeterio, B.P., Romero Fructos-Vazquez, M., Díaz Requejo, M.M., Pérez Romero, P.J.: "Exclusive Aromatic vs Aliphatic C–H Bond Functionalization by Carbene Insertion with Gold-Based Catalysts". Organometallics. Vol. 30 (10), págs. 2855–2860, (2011). DOI: 10.1021/om200206m
dc.identifier.issn1520-6041 (electrónico)
dc.description.abstractThe direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, other Csp3-H bonds remaining unreacted. A study with a several NHC ligands in Au(I) and Au(III) complexes has been performed. A potential application in profen derivatives has also been developeden_US
dc.description.sponsorshipDGI (CTQ2008-00042BQU and Consolider Ingenio 2010, Grant CSD2006-0003) and Junta de Andalucía (P07-FQM-02870)
dc.publisherAmerican Chemical Society
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.subject.otherGold catalysis
dc.subject.otherCarbene transfer
dc.subject.otherC-H functionalization
dc.subject.otherNHC ligands
dc.subject.otherDiazo compounds
dc.titleExclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalystsen_US

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