Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts

Rivilla de la Cruz, Iván; Gómez Emeterio, Bella Pilar; Romero Fructos-Vázquez, Manuel; Díaz Requejo, María Mar; Pérez Romero, Pedro José

doi:10.1021/om200206m

Author

Rivilla de la Cruz, Iván; Gómez Emeterio, Bella Pilar; Romero Fructos-Vázquez, Manuel ; Díaz Requejo, María Mar ; Pérez Romero, Pedro José
Publication Date

2011
Publisher

American Chemical Society
Citation

Rivilla de la Cruz, I., Gómez Emeterio, B.P., Romero Fructos-Vazquez, M., Díaz Requejo, M.M., Pérez Romero, P.J.: "Exclusive Aromatic vs Aliphatic C–H Bond Functionalization by Carbene Insertion with Gold-Based Catalysts". Organometallics. Vol. 30 (10), págs. 2855–2860, (2011). DOI: 10.1021/om200206m
Abstract

The direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, other Csp3-H bonds remaining unreacted. A study with a several NHC ligands in Au(I) and Au(III) complexes has been performed. A potential application in profen derivatives has also been developed
URI

http://hdl.handle.net/10272/11556

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Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts

Author

Rivilla de la Cruz, Iván UHU Authority

; Gómez Emeterio, Bella Pilar; Romero Fructos-Vázquez, Manuel UHU Authority

; Díaz Requejo, María Mar UHU Authority

; Pérez Romero, Pedro José UHU Authority

Publication Date

2011

Publisher

American Chemical Society

Citation

Rivilla de la Cruz, I., Gómez Emeterio, B.P., Romero Fructos-Vazquez, M., Díaz Requejo, M.M., Pérez Romero, P.J.: "Exclusive Aromatic vs Aliphatic C–H Bond Functionalization by Carbene Insertion with Gold-Based Catalysts". Organometallics. Vol. 30 (10), págs. 2855–2860, (2011). DOI: 10.1021/om200206m

Abstract

The direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, other Csp3-H bonds remaining unreacted. A study with a several NHC ligands in Au(I) and Au(III) complexes has been performed. A potential application in profen derivatives has also been developed

URI

http://hdl.handle.net/10272/11556

Fichero	Tamaño	Formato	Ver	Description
Exclusive_aromatic.pdf	509.5Kb	PDF	View/Open	versión post-print

Fichero	Tamaño	Formato	Ver	Description
Exclusive_aromatic.pdf	509.5Kb	PDF	View/Open	versión post-print