Mechanistic and Computational Studies of the Atom Transfer Radical Addition of CCl4 to Styrene Catalyzed by Copper Homoscorpionate Complexes

Muñoz Molina, José María; Saamera, W. M. C.; Maseras, Feliu; Belderrain, Tomás R.; Pérez Romero, Pedro José

doi:10.1021/ic102279w

Author

Muñoz Molina, José María ; Saamera, W. M. C.; Maseras, Feliu; Belderrain, Tomás R.; Pérez Romero, Pedro José
Publication Date

2011-02
Citation

Muñoz Molina,J.M., Saamera, W.M.C., Maseras, F., Belderrain, T.R., Pérez Romero, P.J.: "Mechanistic and Computational Studies of the Atom Transfer Radical Addition of CCl4 to Styrene Catalyzed by Copper Homoscorpionate Complexes". Inorganic Chemistry. Vol. 50 (6), págs. 2458–2467, (2011). DOI: 10.1021/ic102279w
Abstract

Experimental as well as theoretical studies have been carried out with the aim of elucidating the mechanism of the Atom Transfer Radical Addition (ATRA) of styrene and carbon tetrachloride with a TpxCu(NCMe) complex as the catalyst precursor (Tpx = hydrotrispyrazolyl-borate ligand). The studies shown herein demonstrate the effect of different variables in the kinetic behavior. A mechanistic proposal consistent with theoretical and experimental data is presented
URI

http://hdl.handle.net/10272/11554
Project

info:eu-repo/grantAggreement/MICINN [CTQ2008-00042BQU, CTQ2008-06866-CO2-02/BQU, CSD2006-0003]
info:eu-repo/grantAggreement/Junta de Andalucia [P07-FQM-02794]

Fichero	Tamaño	Formato	Ver	Description
Mechanistic_and_computational_studies.pdf	776.9Kb	PDF	View/Open	versión post-print

Fichero	Tamaño	Formato	Ver	Description
Mechanistic_and_computational_studies.pdf	776.9Kb	PDF	View/Open	versión post-print

This item appears in the following Collection(s)

Statistics

View Usage Statistics

Except where otherwise noted, this item's license is described as Atribución-NoComercial-SinDerivadas 3.0 España

Mechanistic and Computational Studies of the Atom Transfer Radical Addition of CCl4 to Styrene Catalyzed by Copper Homoscorpionate Complexes

Author

Muñoz Molina, José María UHU Authority

; Saamera, W. M. C.; Maseras, Feliu; Belderrain, Tomás R.; Pérez Romero, Pedro José UHU Authority

Publication Date

2011-02

Citation

Muñoz Molina,J.M., Saamera, W.M.C., Maseras, F., Belderrain, T.R., Pérez Romero, P.J.: "Mechanistic and Computational Studies of the Atom Transfer Radical Addition of CCl4 to Styrene Catalyzed by Copper Homoscorpionate Complexes". Inorganic Chemistry. Vol. 50 (6), págs. 2458–2467, (2011). DOI: 10.1021/ic102279w

Abstract

Experimental as well as theoretical studies have been carried out with the aim of elucidating the mechanism of the Atom Transfer Radical Addition (ATRA) of styrene and carbon tetrachloride with a TpxCu(NCMe) complex as the catalyst precursor (Tpx = hydrotrispyrazolyl-borate ligand). The studies shown herein demonstrate the effect of different variables in the kinetic behavior. A mechanistic proposal consistent with theoretical and experimental data is presented

URI

http://hdl.handle.net/10272/11554

Project

info:eu-repo/grantAggreement/MICINN [CTQ2008-00042BQU, CTQ2008-06866-CO2-02/BQU, CSD2006-0003]
info:eu-repo/grantAggreement/Junta de Andalucia [P07-FQM-02794]

Fichero

Tamaño

Formato

Ver

Description

Mechanistic_and_computational_studies.pdf

776.9Kb

PDF

View/Open

versión post-print

Fichero

Tamaño