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dc.contributor.authorRomero Fructos-Vázquez, Manuel 
dc.contributor.authorUrbano Baena, Juan 
dc.contributor.authorDíaz Requejo, María Mar 
dc.contributor.authorPérez Romero, Pedro José
dc.identifier.citationRomero Fructos-Vázquez, M., Urbano Baena, J., Díaz Requejo, M.M., Pérez Romero, P.J.: "Evidencing an inner-sphere mechanism for NHC-Au(I)- catalyzed carbene-transfer reactions from ethyl diazoacetate". Beilstein Journal of Organic Chemistry. Vol. 11, págs. 2254–2260, (2015). DOI: 10.3762/bjoc.11.245en_US
dc.identifier.issn1860-5397 (electrónico)
dc.description.abstractKinetic experiments based on the measurement of nitrogen evolution in the reaction of ethyl diazoacetate (N2CHCO2Et, EDA) and styrene or methanol catalyzed by the [IPrAu]+ core (IPr = 1,3-bis(diisopropylphenyl)imidazole-2-ylidene) have provided evidence that the transfer of the carbene group CHCO2Et to the substrate (styrene or methanol) takes place in the coordination sphere of Au(I) by means of an inner-sphere mechanism, in contrast to the generally accepted proposal of outer-sphere mechanisms for Au(I)-catalyzed reactions.en_US
dc.description.sponsorshipSupport for this work was provided by the MINECO (CTQ2014-52769-C3-1-R), and the Junta de Andalucía (P10- FQM-06292).
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.subject.otherCarbene transferen_US
dc.subject.otherInner sphereen_US
dc.subject.otherGold catalysisen_US
dc.subject.otherO–H functionalizationen_US
dc.subject.otherOlefin cyclopropanationen_US
dc.titleEvidencing an inner-sphere mechanism for NHC-Au(I)- catalyzed carbene-transfer reactions from ethyl diazoacetateen_US

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