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Browsing by Subject "C-H functionalization"
Now showing items 1-3 of 3
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Copper‐Catalyzed Selective Pyrrole Functionalization by Carbene Transfer Reaction
Rodríguez, Anabel M.; Molina, Francisco; Díaz Requejo, María Mar
; Pérez Romero, Pedro José (Wiley, 2020-02)
1H‐Pyrroles can be directly functionalized by means of the incorporation of carbene groups from diazo compounds, in a process catalyzed by TpxCu complexes (Tpx=hydrotrispyrazolylborate ligand). The reactions take place ... -
Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts
Rivilla de la Cruz, Iván; Gómez Emeterio, Bella Pilar; Romero Fructos-Vázquez, Manuel; Díaz Requejo, María Mar; Pérez Romero, Pedro José (American Chemical Society, 2011)
The direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, ... -
Silver-Catalyzed C-C Bond Formation between Methane and Ethyl Diazoacetate in Supercritical CO2
Caballero Bevia, Ana; Despagnet-Ayoub, Emmanuelle; Díaz Requejo, María Mar; Díaz Rodríguez, Alba; González Núñez, María Elena; Mello, Rosella; Muñoz, Bianca K.; Ojo, Wilfried-Solo; Asensio, Gregorio; Etienne, Michel; Pérez Romero, Pedro José (American Association for the Advancement of Science, 2011-05)
Even in the context of hydrocarbons’ general resistance to selective functionalization, methane’s volatility and strong bonds pose a particular challenge. We report here that silver complexes bearing perfluorinated ...
