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Intramolecular Interception of the Remote Position of Vinylcarbene Silver Complex Intermediates by C(sp3)−H Bond Insertion
Díaz Jiménez, Àlex; Monreal Corona, Roger; Poater, Albert; Álvarez Martínez, María; Borrego, Elena; Pérez Romero, Pedro José; Caballero Bevia, Ana
; Roglans, Anna; Pla Quintana, Anna (Wiley, 2022)
The trapping of the elusive vinylogous position of a vinyl carbene with an aliphatic C(sp3)−H bond has been achieved for the first time during a silver-catalyzed carbene/alkyne metathesis (CAM) process. A Tpx-containing ...