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Browsing by Author "Rodríguez, Manuel R."
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Catalytic Nitrene Transfer To Alkynes: A Novel and Versatile Route for the Synthesis of Sulfinamides and Isothiazoles
Rodríguez, Manuel R.; Beltrán Martín, Álvaro
; Mudarra, Ángel L.; Álvarez, Eleuterio; Maseras, Feliu; Díaz Requejo, María Mar; Pérez Romero, Pedro José (Wiley, 2017)
A novel transformation is reported for the reaction of terminal or internal alkynes with the nitrene precursor PhI=NTs (Ts=p-toluenesulfonyl) in the presence of catalytic amounts of Tp(Br3)Cu(NCMe) (Tp(Br3)=hydrotris(3,4 ... -
Intermolecular Allene Functionalization by Silver-Nitrene Catalysis
Rodríguez, Manuel R.; Besora, María; Molina, Francisco; Maseras, Feliu; Díaz Requejo, María Mar; Pérez Romero, Pedro José (American Chemical Society, 2020-06)
Under silver catalysis conditions, using [Tp*,BrAg]2 as the catalyst precursor, allenes react with PhI═NTs in the first example of efficient metal-mediated intermolecular nitrene transfer to such substrates. The nature of ... -
Pyrrole Functionalization by Copper‐Catalyzed Nitrene Transfer Reactions
Rodríguez, Anabel M.; Rodríguez, Manuel R.; Díaz Requejo, María Mar; Pérez Romero, Pedro José (Wiley-VCH Verlag, 2020-03)
The catalytic functionalization of pyrroles by incorporation of a nitrene group is reported. The Cα‐H bond of 1H‐pyrrole is amidated upon the formal insertion of the NTs (Ts=p‐toluenesulfonyl) group catalyzed by TpBr3Cu(NCMe) ... -
Trispyrazolylborate Ligands Supported on Vinyl Addition Polynorbornenes and Their Copper Derivatives as Recyclable Catalysts
Molina de la Rorre, Jesús A.; Pérez Ortega, Ignacio; Beltrán Martín, Álvaro; Rodríguez, Manuel R.; Díaz Requejo, María Mar; Pérez Romero, Pedro José; Albéniz, Ana C. (Wiley, 2019)
Polynorbornenes prepared by vinyl addition polymerization and bearing pendant alkenyl groups serve as skeletons to support trispyrazolylborate ligands (Tp(x)) built at those alkenyl sites. Reaction with CuI in acetonitrile ... -
Water as reaction medium for intermolecular C-H alkane functionalization in micellar catalysis
Ávarez, María; Gava, Riccardo; Rodríguez, Manuel R.; Rull, Silvia G.; Pérez Romero, Pedro José (ACS Catalysis, 2017)
A series of alkanes CnH2n+2 have been functionalized in water as the reaction medium, using a silver-based catalyst, upon insertion of carbene (CHCO2Et from N2CHCO2Et) groups into their carbon-hydrogen bonds of ...
