Thesis Collection
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Browsing by Author "Rodríguez, Anabel M."
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Copper‐Catalyzed Selective Pyrrole Functionalization by Carbene Transfer Reaction
Rodríguez, Anabel M.; Molina, Francisco; Díaz Requejo, María Mar
; Pérez Romero, Pedro José (Wiley, 2020-02)
1H‐Pyrroles can be directly functionalized by means of the incorporation of carbene groups from diazo compounds, in a process catalyzed by TpxCu complexes (Tpx=hydrotrispyrazolylborate ligand). The reactions take place ... -
Introducing the Catalytic Amination of Silanes via Nitrene Insertion
Rodríguez, Anabel. M; Pérez Ruíz, Jorge; Molina, Francisco; Poveda, Ana; Pérez Soto, Raúl; Maseras, Feliu; Díaz Requejo, María Mar; Pérez Romero, Pedro José (American Chemical Society, 2022-06-01)
The direct functionalization of Si−H bonds by the nitrene insertion methodology is described. A copper(I) complex bearing a trispyrazolylborate ligand catalyzes the transfer of a nitrene group from PhINTs to the Si−H bond ... -
Pyrrole Functionalization by Copper‐Catalyzed Nitrene Transfer Reactions
Rodríguez, Anabel M.; Rodríguez, Manuel R.; Díaz Requejo, María Mar; Pérez Romero, Pedro José (Wiley-VCH Verlag, 2020-03)
The catalytic functionalization of pyrroles by incorporation of a nitrene group is reported. The Cα‐H bond of 1H‐pyrrole is amidated upon the formal insertion of the NTs (Ts=p‐toluenesulfonyl) group catalyzed by TpBr3Cu(NCMe) ...
