Thesis Collection
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Browsing by Author "Asensio, Gregorio"
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A Quantitative Model for Alkane Nucleophilicity Based on C−H Bond Structural/Topological Descriptors
Besora, María; Olmos Verge, Andrea
; Noverges, Bárbara; Asensio, Gregorio; Caballero Bevia, Ana; Maseras, Feliu; Pérez Romero, Pedro José (Wiley, 2020)
A first quantitative model for calculating the nucleophilicity of alkanes is described. A statistical treatment was applied to the analysis of the reactivity of 29 different alkane C−H bonds towards in situ generated metal ... -
Favoring alkane primary carbon-hydrogen bond functionalization in supercritical carbon dioxide as reaction medium
Sarmiento, Jeymy T.; Olmos Verge, Andrea; Rodríguez Belderraín, Tomás; Caballero Bevia, Ana; Varea, Teresa; Pérez Romero, Pedro José; Asensio, Gregorio (American Chemical Society, 2019)
The selectivity of a catalytic alkane functionalization process can be modified just changing the reaction medium from neat alkane to supercritical carbon dioxide (scCO2). A silica supported copper complex bearing an ... -
Homogeneous Metal-Based Catalysis in Supercritical Carbon Dioxide as Reaction Medium
Olmos Verge, Andrea; Asensio, Gregorio; Pérez Romero, Pedro José (American Chemical Society, 2016)
Above 31.1 degrees C and 73.8 bar, carbon dioxide reaches the supercritical state, being transformed into a fluid (scCO(2)) that has attracted interest in the last few decades as reaction medium for several transition-me ... -
Silver-Catalyzed C-C Bond Formation between Methane and Ethyl Diazoacetate in Supercritical CO2
Caballero Bevia, Ana; Despagnet-Ayoub, Emmanuelle; Díaz Requejo, María Mar; Díaz Rodríguez, Alba; González Núñez, María Elena; Mello, Rosella; Muñoz, Bianca K.; Ojo, Wilfried-Solo; Asensio, Gregorio; Etienne, Michel; Pérez Romero, Pedro José (American Association for the Advancement of Science, 2011-05)
Even in the context of hydrocarbons’ general resistance to selective functionalization, methane’s volatility and strong bonds pose a particular challenge. We report here that silver complexes bearing perfluorinated ...
