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Browsing by Author "Rull, Silvia G."
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Gold-catalyzed ethylene cyclopropanation
Rull, Silvia G.; Olmos Verge, Andrea; Pérez Romero, Pedro José
(Beilstein-Institut, 2019)
Ethylene can be directly converted into ethyl 1-cyclopropylcarboxylate upon reaction with ethyl diazoacetate (N2CHCO2Et, EDA) in the presence of catalytic amounts of IPrAuCl/NaBAr4F (IPr = 1,3-bis(2,6-diisopropylphenyl)i ... -
Water as reaction medium for intermolecular C-H alkane functionalization in micellar catalysis
Ávarez, María; Gava, Riccardo; Rodríguez, Manuel R.; Rull, Silvia G.; Pérez Romero, Pedro José
(ACS Catalysis, 2017)
A series of alkanes CnH2n+2 have been functionalized in water as the reaction medium, using a silver-based catalyst, upon insertion of carbene (CHCO2Et from N2CHCO2Et) groups into their carbon-hydrogen bonds of ...