Thesis Collection
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Browsing by Author "Conde Alcántara, Ana Isabel"
Now showing items 1-4 of 4
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A competing, dual mechanism for catalytic direct benzene hydroxylation from combined experimental-DFT studies
Vilella, Laia; Conde Alcántara, Ana Isabel; Ballcells, David; Díaz Requejo, María Mar
; Lledós, Agustín; Pérez Romero, Pedro José (Royal Society of Chemistry, 2017)
A dual mechanism for direct benzene catalytic hydroxylation is described. Experimental studies and DFT calculations have provided a mechanistic explanation for the acid-free, TpxCu-catalyzed hydroxylation of benzene with ... -
Direct, Copper-Catalyzed Oxidation of Aromatic C-H Bonds with Hydrogen Peroxide under Acid-Free Conditions
Conde Alcántara, Ana Isabel; Díaz Requejo, María Mar; Pérez Romero, Pedro José (Royal Society of Chemistry, 2011-06)
The direct oxidation of benzene into phenol using hydrogen peroxide has been achieved in the absence of any acid with TpxCu(NCMe) complexes as the catalysts. In the case of anthracenes as the substrates, valuable ... -
Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp(2))-H Bonds by Carbene Insertion
Conde Alcántara, Ana Isabel; Sabenya, Gerard; Rodríguez, Mònica; Postils, Verònica; Luis, Josep M.; Díaz Requejo, María Mar; Costas, Miquel; Pérez Romero, Pedro José (Wiley, 2016)
The first examples of the direct functionalization of non-activated aryl sp(2) C-H bonds with ethyl diazoacetate (N2CHCO2Et) catalyzed by Mn- or Fe-based complexes in a completely selective manner are reported, with no ... -
Mechanism of the Selective Fe-Catalyzed Arene Carbon-Hydrogen Bond Functionalization
Postils, Verònica; Rodríguez, Mònica; Sabenya, Gerard; Conde Alcántara, Ana Isabel; Díaz Requejo, María Mar; Pérez Romero, Pedro José; Costas, Miquel; Solà, Miquel; Luis, Josep M. (American Chemical Society, 2018)
The complete chemoselective functionalization of aromatic C(sp(2))-H bonds of benzene and alkyl benzenes by carbene insertion from ethyl diazoacetate was unknown until the recent discovery of an iron-based catalytic system ...
