Thesis Collection
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Browsing by Author "Rivilla de la Cruz, Iván"
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Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts
Rivilla de la Cruz, Iván
; Gómez Emeterio, Bella Pilar; Romero Fructos-Vázquez, Manuel; Díaz Requejo, María Mar; Pérez Romero, Pedro José (American Chemical Society, 2011)
The direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, ... -
Gold-catalyzed naphthalene functionalization
Pérez Romero, Pedro José; Díaz Requejo, María Mar; Rivilla de la Cruz, Iván (Beilstein-Institut, 2011)
The complexes IPrMCl (IPr = 1,3-bis(diisopropylphenyl)imidazol-2-ylidene, M = Cu, 1a; M = Au, 1b) in the presence of one equiv of NaBAr’4 (Ar’ = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) catalyze the transfer of ...
