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Browsing by Author "Muñoz Molina, José María"
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Atom Transfer Radical Reactions as a Tool for Olefin Functionalization : On the Way to Practical Applications
Muñoz Molina, José María
; Rodríguez Belderraín, Tomás; Pérez Romero, Pedro José (Wiley-VCH Verlag, 2011)
Transition-metal-catalyzed atom transfer radical reactions of halogenated compounds with olefins constitute a versatile tool in organic synthesis within the area of C–C bond forming transformations. The inter- or intramolecular ... -
Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N–F reagents
Muñoz Molina, José María; Rodríguez Belderraín, Tomás; Pérez Romero, Pedro José (Royal Society of Chemistry, 2020-10)
The mild generation of nitrogen-centred radicals from N–F reagents has become a convenient synthetic tool. This methodology provides access to the aminative difunctionalisation of alkenes and alkynes and the radical ... -
Copper-Catalyzed N-F Bond Activation for Uniform Intramolecular C-H Amination Yielding Pyrrolidines and Piperidines
Bafaluy, Daniel; Muñoz Molina, José María; Funes Ardoiz, Ignacio; Herold, Sebastian; Aguirre, Adiran J. de; Zhang, Hongwei; Maseras, Feliu; Rodríguez Belderraín, Tomás; Pérez Romero, Pedro José; Muñiz, Kilian (Wiley, 2019-06)
The dual function of the N-F bond as an effective oxidant and subsequent nitrogen source in intramolecular aliphatic C-H functionalization reactions is explored. Copper catalysis is demonstrated to exercise full regio- and ... -
Group 11 tris(pyrazolyl)methane complexes: structural features and catalytic applications
Muñoz Molina, José María; Rodríguez Belderraín, Tomás; Pérez Romero, Pedro José (Royal Society of Chemistry, 2019)
Tris(pyrazolyl)methane ligands (Tpmx) have been for years a step behind their highly popular boron-anionic analogues, the tris(pyrazolyl)borate ligands (Tpx). However, in the last decade the development of new members of ... -
Mechanistic and Computational Studies of the Atom Transfer Radical Addition of CCl4 to Styrene Catalyzed by Copper Homoscorpionate Complexes
Muñoz Molina, José María; Saamera, W. M. C.; Maseras, Feliu; Belderrain, Tomás R.; Pérez Romero, Pedro José (2011-02)
Experimental as well as theoretical studies have been carried out with the aim of elucidating the mechanism of the Atom Transfer Radical Addition (ATRA) of styrene and carbon tetrachloride with a TpxCu(NCMe) complex as the ... -
Mechanistic Studies on the Synthesis of Pyrrolidines and Piperidines via Copper-Catalyzed Intramolecular C–H Amination
Muñoz Molina, José María; Bafaluy, Daniel; Funes Ardoiz, Ignacio; Aguirre, Adiran J. de; Maseras, Feliu; Rodríguez Belderraín, Tomás; Pérez Romero, Pedro José; Muñiz, Kilian (American Chemical Society, 2022)
We have recently developed a method for the synthesis of pyrrolidines and piperidines via intramolecular C–H amination of N-fluoride amides using [TpxCuL] complexes as precatalysts [Tpx = tris(pyrazolyl)borate ligand and ... -
Recent Advances in Copper-Catalyzed Radical C–H Bond Activation Using N–F Reagents
Muñoz Molina, José María; Rodríguez Belderraín, Tomás; Pérez Romero, Pedro José (Thieme Gruppe, 2021)
This Short Review is aimed at giving an update in the area of copper-catalyzed C–H functionalization involving nitrogen-centered radicals generated from substrates containing N–F bonds. These processes include intermolecular ... -
Ruthenium-Catalyzed Heck-Type Alkenylation of Alkyl Bromides
Muñoz Molina, José María; Pérez Romero, Pedro José (American Chemical Society, 2019-05-27)
The complex [Cp*RuCl(PPh3)2] displays a high catalytic activity for the Heck-type alkenylation of alkyl bromides, in the first example using this metal under thermal conditions. The coupling reaction proceeds efficiently ... -
Trispyrazolylborate coinage metals complexes : structural features and catalytic transformations
Muñoz Molina, José María; Rodríguez Belderraín, Tomás; Pérez Romero, Pedro José (Elsevier, 2019)
Tris(pyrazolyl)borates (Tpx) have become one of the most broadly used polydentate anionic ligands in coordination chemistry and catalysis since Trofimenko introduced them in 1966. Herein we present a review of the main ...
