Thesis Collection
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Browsing by Author "Gava, Riccardo"
Now showing items 1-5 of 5
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Copper-Catalyzed Dehydrogenative Amidation of Light Alkanes
Fuentes Domínguez, María Ángeles
; Gava, Riccardo; Saper, Noam I.; Romero, Erik A.; Caballero Bevia, Ana; Hartwig, John F.; Pérez Romero, Pedro José (Wiley, 2021-05)
The functionalization of C-H bonds in light alkanes, particularly to form C-N bonds, remains a challenge. We report the dehydrogenative coupling of amides with C1–C4 hydrocarbons to form N-alkyl amide products with tBuOOtBu ... -
Funcionalización catalítica de metano y alcanos ligeros con complejos metálicos del grupo 11
Gava, Riccardo (Universidad de Huelva, 2017)
The main objectives in this Ph. D. Thesis are focused in the development of catalytic systems toward the functionalization of highly inert molecules such as gaseous alkanes (CnH2n+-2, n = 1-4). The reaction employed toward ... -
Measuring the Relative Reactivity of the Carbon-Hydrogen Bonds of Alkanes as Nucleophiles
Olmos Verge, Andrea; Gava, Riccardo; Caballero Bevia, Ana; Pérez Romero, Pedro José (Wiley, 2018)
We report quantitative measurements of the relative reactivities of a series of C-H bonds of gaseous or liquid CnH2n+2 alkanes (n = 1-8, 29 different C-H bonds) towards insitu generated electrophiles (copper, silver, and ... -
Methane functionalization in water with micellar catalysis
Gava, Riccardo; Ballestin, Pilar; Prieto Cárdenas, María Auxiliadora; Caballero Bevia, Ana; Pérez Romero, Pedro José (Royal Society of Chemistry, 2019-08)
The functionalization of methane in water as the reaction medium (where it is nearly insoluble) at room temperature using micellar catalysis is described. Aggregates are formed from surfactant molecules and act as methane ... -
Water as reaction medium for intermolecular C-H alkane functionalization in micellar catalysis
Ávarez, María; Gava, Riccardo; Rodríguez, Manuel R.; Rull, Silvia G.; Pérez Romero, Pedro José (ACS Catalysis, 2017)
A series of alkanes CnH2n+2 have been functionalized in water as the reaction medium, using a silver-based catalyst, upon insertion of carbene (CHCO2Et from N2CHCO2Et) groups into their carbon-hydrogen bonds of ...
