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Browsing by Author "Borrego, Elena"
Now showing items 1-4 of 4
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Direct Benzene Hydroxylation with Dioxygen Induced by Copper Complexes: Uncovering the Active Species by DFT Calculations
Borrego, Elena; Tiessler Sala, Laura; Lázaro, Jesús J.; Caballero Bevia, Ana
; Pérez Romero, Pedro José; Lledós, Agustí (America Chemical Society, 2022-07-14)
The direct oxidation of benzene into phenol using molecular oxygen at very mild temperatures can be promoted in the presence of the copper complex TpBr3Cu(NCMe) in the homogeneous phase in the presence of ascorbic acid as ... -
Intramolecular Interception of the Remote Position of Vinylcarbene Silver Complex Intermediates by C(sp3)−H Bond Insertion
Díaz Jiménez, Àlex; Monreal Corona, Roger; Poater, Albert; Álvarez Martínez, María; Borrego, Elena; Pérez Romero, Pedro José; Caballero Bevia, Ana; Roglans, Anna; Pla Quintana, Anna (Wiley, 2022)
The trapping of the elusive vinylogous position of a vinyl carbene with an aliphatic C(sp3)−H bond has been achieved for the first time during a silver-catalyzed carbene/alkyne metathesis (CAM) process. A Tpx-containing ... -
Make It Green: Copper-Catalyzed Olefin Aziridination in Water with an Iminoiodonane
Borrego, Elena; Pérez Romero, Pedro José; Caballero Bevia, Ana (Wiley, 2021)
The copper complex Tp(CF3)2,BrCu(NCMe) efficiently catalyses the aziridination of olefins in water using PhI=NTs as the nitrene source, with identical activity than that observed when using dichloromethane as the solvent, ... -
Micellar Catalysis as a Tool for C-H Bond Functionalization To-ward C-C Bond Formation
Borrego, Elena; Caballero Bevia, Ana; Pérez Romero, Pedro José (American Chemical Society, 2022-11-28)
Micelles generated upon dissolving surfactants in water can be employed as nano-vessels for catalytic transformations, in the so-called micellar catalysis methodology. This review is focused onto the use of micellar ...
