@article{10272/21359,
year = {2022},
month = {11},
url = {https://hdl.handle.net/10272/21359},
abstract = {Complexes [(NHC)MCl] (M = coinage metal) have been evaluated as catalyst for the olefin aziridination reaction using PhI=NTs as nitrene source, with moderate to high activity being found depending of the metal and the olefin. At variance with frequently employed copper catalysts with bi-, tri- or tetradentate, N-donor ligands, these monodentante, C-donor ligand infer a remarkable effect in the reaction mechanism. Experimental evidences support the proposal of a concerted mechanism and the absence of radical intermediates, which are the commonly proposed species involved in these nitrene transfer reactions.},
organization = {We thank to Ministerio de Ciencia e Innovación for Grant PID2020-113797RB-C21, also financed by FEDER “Una manera de hacer Europa”. We also thank Junta de Andalucía (P20-00348) and Universidad de Huelva (P.O.Feder UHU-202016).},
publisher = {American Chemical Society},
keywords = {Aziridines},
keywords = {Catalysts},
keywords = {Hydrocarbons},
keywords = {Ligands},
keywords = {Transfer reactions},
title = {(NHC)M Cores as Catalysts for the Olefin Aziridination Reaction (M= Cu, Ag, Au): Evidencing a Concerted Mechanism for the Nitrene Transfer Process},
doi = {10.1021/acs.organomet.2c00310},
author = {Pérez Ruíz, Jorge and Díaz Requejo, María Mar and Pérez Romero, Pedro José},
}