@article{10272/21357,
year = {2022},
month = {2},
url = {https://hdl.handle.net/10272/21357},
abstract = {Gold nanoparticles stabilized by NHC ligands and supported onto reduced graphene oxide (rGO) catalyse the functionalization of cyclohexane and benzene C-H bonds upon insertion of carbene CHCO2Et (from N2=CHCO2Et) groups. This is the first example in which such Csp3 or Csp2 bonds are functionalized with this strategy with nanoparticulated gold. This Au-NP@rGO material shows an exceptional activity, providing TON values 5-10 times higher than those already reported for molecular gold catalysts. Recyclability is also effective, reaching an accumulate TON value of 1400 after six consecutive uses},
organization = {We thank to Ministerio de Ciencia e Innovación for Grants PID2020-113797RB-C21, RTI2018-098237-B-C22 and PID2019-105881RB-I00 also financed by FEDER “Una manera de hacer Europa”. We also thank Junta de Andalucía (P18-RT-1536) and Universidad de Huelva (P.O.Feder UHU-1260216). JML thanks Ministerio de Ciencia e Innovación for FPI fellowship. A. M-C. thanks Generalitat Valenciana for grant (ACIF/2019/100). S. M. acknowledges DGA/fondos FEDER (Construyendo Europa desde Aragón) for funding the research group Platón (E31_20R).},
publisher = {Royal Society of Chemistry},
title = {Gold nanoparticle-catalysed functionalization of carbon-hydrogen bonds by carbene transfer reactions},
doi = {10.1039/D1DT04351J},
author = {Martínez Laguna, Jonathan and Mollar Cuni, Andres and Ventura Espinosa, David and Martín, Santiago and Caballero Bevia, Ana and Mata, Jose A. and Pérez Romero, Pedro José},
}