@article{10272/11556,
year = {2011},
url = {http://hdl.handle.net/10272/11556},
abstract = {The direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, other Csp3-H bonds remaining unreacted. A study with a several NHC ligands in Au(I) and Au(III) complexes has been performed. A potential application in profen derivatives has also been developed},
organization = {DGI (CTQ2008-00042BQU and Consolider Ingenio 2010, Grant CSD2006-0003) and Junta de Andalucía (P07-FQM-02870)},
publisher = {American Chemical Society},
keywords = {Gold catalysis},
keywords = {Carbene transfer},
keywords = {C-H functionalization},
keywords = {NHC ligands},
keywords = {Diazo compounds},
title = {Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts},
doi = {10.1021/om200206m},
author = {Rivilla de la Cruz, Iván and Gómez Emeterio, Bella Pilar and Romero Fructos-Vázquez, Manuel and Díaz Requejo, María Mar and Pérez Romero, Pedro José},
}