@article{10272/11486,
year = {2015},
url = {http://hdl.handle.net/10272/11486},
abstract = {Kinetic experiments based on the measurement of nitrogen evolution in the reaction of ethyl diazoacetate (N2CHCO2Et, EDA) and
styrene or methanol catalyzed by the [IPrAu]+ core (IPr = 1,3-bis(diisopropylphenyl)imidazole-2-ylidene) have provided evidence
that the transfer of the carbene group CHCO2Et to the substrate (styrene or methanol) takes place in the coordination sphere of
Au(I) by means of an inner-sphere mechanism, in contrast to the generally accepted proposal of outer-sphere mechanisms for
Au(I)-catalyzed reactions.},
organization = {Support  for  this  work  was  provided  by  the  MINECO
(CTQ2014-52769-C3-1-R), and the Junta de Andalucía (P10-
FQM-06292).},
publisher = {Beilstein-Institut},
keywords = {Carbene transfer},
keywords = {Inner sphere},
keywords = {Gold catalysis},
keywords = {O–H functionalization},
keywords = {Olefin cyclopropanation},
title = {Evidencing an inner-sphere mechanism for NHC-Au(I)- catalyzed carbene-transfer reactions from ethyl diazoacetate},
doi = {10.3762/bjoc.11.245},
author = {Romero Fructos-Vázquez, Manuel and Urbano Baena, Juan and Díaz Requejo, María Mar and Pérez Romero, Pedro José},
}