Browsing DQCM - Artículos by Author
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Browsing DQCM - Artículos by Author "Olmos Verge, Andrea"
Miguel Ávila, Joan; Tomás Gamasa, María; Olmos Verge, Andrea; Pérez Romero, Pedro José; Mascareñas, José L. (Royal Society of Chemistry, 2018)The archetype reaction of “click” chemistry, namely, the copper-promoted azide–alkyne cycloaddition (CuAAC), has found an impressive number of applications in biological chemistry. However, methods for promoting intermolecular ...
Favoring alkane primary carbon-hydrogen bond functionalization in supercritical carbon dioxide as reaction medium Sarmiento, Jeymy T.; Olmos Verge, Andrea; Rodríguez Belderraín, Tomás; Caballero Bevia, Ana; Varea, Teresa; Pérez Romero, Pedro José; Asensio, Gregorio (American Chemical Society, 2019)The selectivity of a catalytic alkane functionalization process can be modified just changing the reaction medium from neat alkane to supercritical carbon dioxide (scCO2). A silica supported copper complex bearing an ...
Ethylene can be directly converted into ethyl 1-cyclopropylcarboxylate upon reaction with ethyl diazoacetate (N2CHCO2Et, EDA) in the presence of catalytic amounts of IPrAuCl/NaBAr4F (IPr = 1,3-bis(2,6-diisopropylphenyl)i ...
Above 31.1 degrees C and 73.8 bar, carbon dioxide reaches the supercritical state, being transformed into a fluid (scCO(2)) that has attracted interest in the last few decades as reaction medium for several transition-me ...
We report quantitative measurements of the relative reactivities of a series of C-H bonds of gaseous or liquid CnH2n+2 alkanes (n = 1-8, 29 different C-H bonds) towards insitu generated electrophiles (copper, silver, and ...
Olmos Verge, Andrea; Pereira Pérez, Ana; Rodríguez Belderraín, Tomás; Pérez Romero, Pedro José (Thieme Publishing, 2018)A multigram method for the preparation of thallium trispyrazolylborate complexes is described.