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dc.contributor.authorGonzález Rull, Silvia 
dc.contributor.authorÁlvarez, Eleuterio
dc.contributor.authorRomero Fructos-Vázquez, Manuel 
dc.contributor.authorRodríguez Belderraín, Tomás 
dc.contributor.authorPérez Romero, Pedro José
dc.identifier.citationGonzález Rull, S., Álvarez, E., Fructos, M. R., Belderrain, T. R., & Pérez, P. J. (2017). The Elusive Palladium-Diazo Adduct Captured: Synthesis, Isolation and Structural Characterization of [(ArNHC-PPh2 )Pd(η2 -N2 C(Ph)CO2 Et)]. Chemistry - A European Journal, 23(32), 7667-7671.
dc.identifier.issn1521-3765 (electrónico)
dc.description.abstractThe first example of a diazo palladium adduct is reported. The complexes [(ArNHC-PPh2) M(eta(N2C)-N-2(Ph) CO2Et)] (M = Ni, 3; M = Pd, 4; ArNHC-PPh2 = 3-(2,6-diisopropylphenyl)- 1-[(diphenylphosphino)ethyl] imidazol-2-ylidene) were prepared by ligand exchange with styrene-coordinated precursors [(ArNHC @ PPh2) M(styrene)] (M = Ni, 1; M = Pd, 2). Complex 4 was fully characterized, including X-ray analyses; this constitutes the first example of a diazo adduct compound with palladium, thereby closing the gap between Groups 8 and 10 regarding this type of compounds.es_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.subject.otherCarbene transferes_ES
dc.subject.otherDiazo ligandses_ES
dc.subject.otherNhc-phosphine ligandes_ES
dc.subject.otherPalladium(0) complexeses_ES
dc.subject.otherPalladium diazo adductes_ES
dc.titleThe Elusive Palladium-Diazo Adduct Captured: Synthesis, Isolation and Structural Characterization of [(ArNHC-PPh2)Pd(eta(2)-N2C(Ph)CO2Et)]es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO [CTQ2014-52769-C03-01 and CTQ2011-24502]es_ES

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