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dc.contributor.authorOlmos Verge, Andrea 
dc.contributor.authorGava, Riccardo 
dc.contributor.authorCaballero Bevia, Ana 
dc.contributor.authorPérez Romero, Pedro José 
dc.date.accessioned2019-02-13T13:39:23Z
dc.date.available2019-02-13T13:39:23Z
dc.date.issued2018
dc.identifier.citationOlmos, A., Gava, R., Noverges, B., Bellezza, D., Jacob, K., Besora, M., Caballero Bevia, A., Pérez Romero, P. J. (2018). Measuring the Relative Reactivity of the Carbon-Hydrogen Bonds of Alkanes as Nucleophiles. Angewandte Chemie International Edition, 57(42), 13848-13852. https://doi.org/10.1002/anie.201807448es_ES
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773 electrónico
dc.identifier.urihttp://hdl.handle.net/10272/15974
dc.description.abstractWe report quantitative measurements of the relative reactivities of a series of C-H bonds of gaseous or liquid CnH2n+2 alkanes (n = 1-8, 29 different C-H bonds) towards insitu generated electrophiles (copper, silver, and rhodium carbenes), with methane as the reference. This strategy surpasses the drawback of previous model reactions of alkanes with strong electrophiles suffering from C-C cleavage processes, which precluded direct comparison of the relative reactivities of alkane C-H bonds.es_ES
dc.description.sponsorshipWe thank MINECO for support with Grants CTQ2014-52769-C03-01, CTQ2014-52769-C03-02, CTQ2017-82893-C2-1-R, CTQ2014-62234-EXP, CTQ2015-73693-JIN, CTQ2017-87792-R, Severo Ochoa Excellence Accreditation 2014-2018 (SEV-2013-0319), and Red Intecat (CTQ2016-81923-REDC). Junta de Andalucia is also acknowledged for Grant P12-FQM-1765. R.G. and A.O. thank MINECO for FPI and Juan delaCierva fellowships, respectively. B.N. thanks MEC for a FPU fellowship. The CNRS is thanked for support.es_ES
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherAlkaneses_ES
dc.subject.otherC-H bond functionalizationes_ES
dc.subject.otherElectrophilicityes_ES
dc.subject.otherMetal carbene complexeses_ES
dc.subject.otherNucleophilicityes_ES
dc.titleMeasuring the Relative Reactivity of the Carbon-Hydrogen Bonds of Alkanes as Nucleophileses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherversionhttps://doi.org/10.1002/anie.201807448es_ES
dc.identifier.doi10.1002/anie.201807448
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO [CTQ2014-52769-C03-01, CTQ2014-52769-C03-02, CTQ2017-82893-C2-1-R, CTQ2014-62234-EXP, CTQ2015-73693-JIN, CTQ2017-87792-R]es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/Junta de Andalucia [P12-FQM-1765]


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