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dc.contributor.authorOlmos Verge, Andrea 
dc.contributor.authorGava, Riccardo 
dc.contributor.authorCaballero Bevia, Ana 
dc.contributor.authorPérez Romero, Pedro José
dc.identifier.citationOlmos, A., Gava, R., Noverges, B., Bellezza, D., Jacob, K., Besora, M., Caballero Bevia, A., Pérez Romero, P. J. (2018). Measuring the Relative Reactivity of the Carbon-Hydrogen Bonds of Alkanes as Nucleophiles. Angewandte Chemie International Edition, 57(42), 13848-13852.
dc.identifier.issn1521-3773 electrónico
dc.description.abstractWe report quantitative measurements of the relative reactivities of a series of C-H bonds of gaseous or liquid CnH2n+2 alkanes (n = 1-8, 29 different C-H bonds) towards insitu generated electrophiles (copper, silver, and rhodium carbenes), with methane as the reference. This strategy surpasses the drawback of previous model reactions of alkanes with strong electrophiles suffering from C-C cleavage processes, which precluded direct comparison of the relative reactivities of alkane C-H bonds.es_ES
dc.description.sponsorshipWe thank MINECO for support with Grants CTQ2014-52769-C03-01, CTQ2014-52769-C03-02, CTQ2017-82893-C2-1-R, CTQ2014-62234-EXP, CTQ2015-73693-JIN, CTQ2017-87792-R, Severo Ochoa Excellence Accreditation 2014-2018 (SEV-2013-0319), and Red Intecat (CTQ2016-81923-REDC). Junta de Andalucia is also acknowledged for Grant P12-FQM-1765. R.G. and A.O. thank MINECO for FPI and Juan delaCierva fellowships, respectively. B.N. thanks MEC for a FPU fellowship. The CNRS is thanked for support.es_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.subject.otherC-H bond functionalizationes_ES
dc.subject.otherMetal carbene complexeses_ES
dc.titleMeasuring the Relative Reactivity of the Carbon-Hydrogen Bonds of Alkanes as Nucleophileses_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO [CTQ2014-52769-C03-01, CTQ2014-52769-C03-02, CTQ2017-82893-C2-1-R, CTQ2014-62234-EXP, CTQ2015-73693-JIN, CTQ2017-87792-R]es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/Junta de Andalucia [P12-FQM-1765]

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