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Catalytic Functionalization of C-H Bonds of Azulene by Carbene/Nitrene Incorporation
| dc.contributor.author | Carreras, Javier | |
| dc.contributor.author | Popowski, Yanay | |
| dc.contributor.author | Caballero Bevia, Ana | |
| dc.contributor.author | Amir, Elizabeth | |
| dc.contributor.author | Pérez Romero, Pedro José | |
| dc.date.accessioned | 2019-02-13T13:19:21Z | |
| dc.date.available | 2019-02-13T13:19:21Z | |
| dc.date.issued | 2018 | |
| dc.identifier.citation | Carreras, J., Popowski, Y., Caballero, A., Amir, E., & Pérez, P. J. (2018). Catalytic Functionalization of C–H Bonds of Azulene by Carbene/Nitrene Incorporation. The Journal of Organic Chemistry, 83(18), 11125-11132. https://doi.org/10.1021/acs.joc.8b01731 | es_ES |
| dc.identifier.issn | 0022-3263 | |
| dc.identifier.issn | 1520-6904 electrónico | |
| dc.identifier.uri | http://hdl.handle.net/10272/15973 | |
| dc.description.abstract | The selective catalytic functionalization of the C-H bond of azulene upon incorporation of carbene or nitrene units with metal-based catalysts is described. Ethyl diazoacetate or ArI=NTs are employed as carbene or nitrene precursors, respectively. The azulene derivatives are subsequently employed as building blocks toward more complex structures with potential use as biodegradable materials. | es_ES |
| dc.description.sponsorship | We thank MINECO (CTQ2017-82893-C2-1-R and Juan de la Cierva fellowship for J.C.), Junta de Andalucia for Grant P12-FQM-1765, and CHAOS COST ACTION CA-15106. We also thank Manuel A. Pulido for preliminary experiments and Francisco Molina for X-ray structure determination. | es_ES |
| dc.language.iso | eng | es_ES |
| dc.publisher | American Chemical Society | es_ES |
| dc.rights | Atribución-NoComercial-SinDerivadas 3.0 España | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | * |
| dc.subject.other | Catalytic | es_ES |
| dc.subject.other | Azulene | es_ES |
| dc.title | Catalytic Functionalization of C-H Bonds of Azulene by Carbene/Nitrene Incorporation | es_ES |
| dc.type | info:eu-repo/semantics/article | es_ES |
| dc.relation.publisherversion | https://doi.org/10.1021/acs.joc.8b01731 | es_ES |
| dc.identifier.doi | 10.1021/acs.joc.8b01731 | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/MINECO [CTQ2017-82893-C2-1-R] | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/unta de Andalucia [P12-FQM-1765] |
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