Gold-catalyzed ethylene cyclopropanation
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Publication Date
2019 -
Publisher
Beilstein-Institut -
Citation
Rull, S. G., Olmos, A., & Pérez, P. J. (2019). Gold-catalyzed ethylene cyclopropanation. Beilstein Journal of Organic Chemistry, 15, 67-71. https://doi.org/10.3762/bjoc.15.7 -
Abstract
Ethylene can be directly converted into ethyl 1-cyclopropylcarboxylate upon reaction with ethyl diazoacetate (N2CHCO2Et, EDA) in the presence of catalytic amounts of IPrAuCl/NaBAr4F (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene, BAr4F = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate). -
Project
info:eu-repo/grantAgreement/MINECO [TQ2017-82893-C2-1-R and CTQ2015-73693-JIN]
Fichero | Tamaño | Formato |
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Gold-catalyzed.pdf | 320.2Kb | View/ | versión editor |
Fichero | Tamaño | Formato |
| Description |
---|---|---|---|---|
Gold-catalyzed.pdf | 320.2Kb | View/ | versión editor |