Gold-catalyzed ethylene cyclopropanation

Rull, Silvia G.; Olmos Verge, Andrea; Pérez Romero, Pedro José

doi:10.3762/bjoc.15.7

Author

Rull, Silvia G.; Olmos Verge, Andrea ; Pérez Romero, Pedro José
Publication Date

2019
Publisher

Beilstein-Institut
Citation

Rull, S. G., Olmos, A., & Pérez, P. J. (2019). Gold-catalyzed ethylene cyclopropanation. Beilstein Journal of Organic Chemistry, 15, 67-71. https://doi.org/10.3762/bjoc.15.7
Abstract

Ethylene can be directly converted into ethyl 1-cyclopropylcarboxylate upon reaction with ethyl diazoacetate (N2CHCO2Et, EDA) in the presence of catalytic amounts of IPrAuCl/NaBAr4F (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene, BAr4F = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate).
URI

http://hdl.handle.net/10272/15934
Project

info:eu-repo/grantAgreement/MINECO [TQ2017-82893-C2-1-R and CTQ2015-73693-JIN]

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Gold-catalyzed ethylene cyclopropanation

Author

Rull, Silvia G.; Olmos Verge, Andrea UHU Authority

; Pérez Romero, Pedro José UHU Authority

Publication Date

2019

Publisher

Beilstein-Institut

Citation

Rull, S. G., Olmos, A., & Pérez, P. J. (2019). Gold-catalyzed ethylene cyclopropanation. Beilstein Journal of Organic Chemistry, 15, 67-71. https://doi.org/10.3762/bjoc.15.7

Abstract

Ethylene can be directly converted into ethyl 1-cyclopropylcarboxylate upon reaction with ethyl diazoacetate (N2CHCO2Et, EDA) in the presence of catalytic amounts of IPrAuCl/NaBAr4F (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene, BAr4F = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate).

URI

http://hdl.handle.net/10272/15934

Project

info:eu-repo/grantAgreement/MINECO [TQ2017-82893-C2-1-R and CTQ2015-73693-JIN]

Fichero	Tamaño	Formato	Ver	Description
Gold-catalyzed.pdf	320.2Kb	PDF	View/Open	versión editor

Fichero	Tamaño	Formato	Ver	Description
Gold-catalyzed.pdf	320.2Kb	PDF	View/Open	versión editor