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dc.contributor.authorFuentes, M. Ángeles
dc.contributor.authorRodríguez Castillo, María
dc.contributor.authorMonge, Miguel
dc.contributor.authorOlmos, M. Elena
dc.contributor.authorLópez de Luzuriaga, José M.
dc.contributor.authorCaballero Bevia, Ana 
dc.contributor.authorPérez Romero, Pedro José 
dc.date.accessioned2016-01-11T08:50:26Z
dc.date.available2016-01-11T08:50:26Z
dc.date.issued2011
dc.identifier.citationFuentes, M.A., Rodríguez Castillo, M., Monge, M., Olmos, M. Elena, López de Luzuriaga, J.M., Caballero Bevia, A., Pérez Romero, P.J.: "Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate : gold as a ligand". Inorganica Chimica Acta. Vol. 369, n. 1, págs. 146-149, (2011). DOI: 10.1016/j.ica.2011.01.012
dc.identifier.issn0020-1693
dc.identifier.urihttp://hdl.handle.net/10272/11555
dc.description.abstractThe complexes [Au2M2(C6F5)4(NCMe)2]n (M = Cu, 1; M = Ag, 2) have been tested as catalysts for the functionalization of alkanes by the carbene insertion methodology, using ethyl diazoacetate as the carbene source. Moderate to high conversions have been obtained. The observed selectivities seem to favor the proposal that the active metal for catalysis is the Cu/Ag center, the Au(C6F5)2 unit acting as a spectator ligand in both cases.en_US
dc.description.sponsorshipDGI for funding (CTQ2008-00042/BQU and CTQ2010-20500-C02-02)en_US
dc.language.isoengen_US
dc.publisherElsevier
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherC–H functionalization
dc.subject.otherDiazocompounds
dc.subject.otherCarbenes
dc.subject.otherCoinage metals
dc.titleIntermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate : gold as a liganden_US
dc.typeinfo:eu-repo/semantics/articleen_US
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.ica.2011.01.012
dc.identifier.doi10.1016/j.ica.2011.01.012
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen_US


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